Using the Kf value of 1.2×109 calculate the concentration of Ni2+(aq) and Ni(NH3)62+ that are present at equilibrium after dissolving 1.47 gNiCl2 in 100.0 mL of NH3(aq) solution such that the equilibrium concentration of NH3 is equal to 0.20 M.
Express your answers in moles per liter to two significant figures separated by a comma.

Answers

Answer 1

This problem is describing the equilibrium whereby the formartion of a complex is attained when 1.47 g of nickel(II) chloride is dissolved in 100.0 mL of ammonia so that the latter's equilibium concentration is 0.20 M. Thus, it is asked to calculate the equilibrium concentrations of both nickel(II) ions and that of the complex.

Firstly, we can write out the chemical equation to be considered:

[tex]Ni^{2+}+6NH_3\rightleftharpoons Ni(NH_3)_6^{2+}[/tex]

Next, we can calculate the initial concentration of nickel(II) ions by using the concept of molarity:

[tex][Ni^{2+}]=\frac{1.47gNiCl_2*\frac{1molNiCl_2}{129.6g}*\frac{1molNi^{2+}}{1molNiCl_2} }{0.1000L}=0.113M[/tex]

Afterwards, we set up an equilibrium expression for this chemical reaction:

[tex]Kf=\frac{[Ni(NH_3)_6^{2+}]}{[Ni^{2+}][NH_3]^6}[/tex]

Which can be written in terms of the reaction extent, [tex]x[/tex]:

[tex]Kf=\frac{x}{(0.113-x)(0.2)^6}[/tex]

Now, for the calculation of [tex]x[/tex], we plug in Kf, and solve for it:

[tex]1.2x10^9=\frac{x}{(0.113-x)(0.2)^6}\\\\1.2x10^9=\frac{x}{(0.113-x)(6.4x10^{-5})}\\\\7.68x10^4(0.113-x)=x\\\\x=0.112999 M[/tex]

Which is about the same to the initial concentration of nickel(II) ions because the Kf is too large.

Thus, the required concentrations at equilibrium are about:

[tex][Ni(NH_3)_6^{2+}]=0.113M[/tex]

[tex][Ni^{2+}]=0M[/tex]

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Related Questions

4. Use the atomic model to answer the following questions

A. How many protons?

B. How many neutrons?

C. What is the name of this atom?​

Answers

Answer:

´protons: 16

neutrons: 16

name: sulfur

Explanation:

A buffer solution was prepared by mixing 50.0 mL of a 0.100 M solution of CH3COOH with 0.500 grams of NaCH3COO. The resulting mixture is diluted to 100.0 mL. What is the pH of the solution

Answers

Answer:

100.0

Explanation:

Have a great day god bless

Which solution has the same number of moles of KCl as 75.00 mL of 0.250 M solution of KCl?
25.0 mL of 0.175 M solution of KCl
129 mL of 0.145 M solution of KCl
20.0 mL of 0.200 M solution of KCl
50.0 mL of 0.125 M solution of KCl
100 mL of 0.0500 M solution of KCl

Answers

Answer:

None of them

Explanation:

The number of moles in 75ml is 0.01875moles while in 25ml is 0.004375 and in 129 ml is 0.018705.

REMEMBER: Molarity is the number of moles per litre so in order to get the number of moles you multiply the molarity of the substance by the quantity of the substance in litres.

129 mL of 0.145 M solution of KCl solution has the same number of moles of KCl as 75.00 mL of 0.250 M solution of KCl. Therefore, option B is correct.

What is molarity ?

Molarity is defined as the number of moles of a solute in one liter of solution. A solution's molarity is also known as its molar concentration.

To calculate the molarity of a solution, divide the number of moles of solute by the total volume of solution in liters.

Molarity is a concentration unit that is defined as the number of moles of dissolved solute per liter of solution. Molarity is expressed as the number of millimoles per milliliter of solution when the number of moles and volume are divided by 1000.

Given:

number of mol = M ×V

= 0.250 M × 0.0750 L

= 1.87 × 10^-2 mol

volume, V = 1.29*10^2 mL

= 0.129 L

use:

number of mol,

n = Molarity × Volume

= 0.145 × 0.129

= 1.87 × 10^-2 mol

Thus, option B is correct.

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Hello, is there anyone here a pharmacy technician?

Answers

Explanation:

It can take up to two years to become a pharmacy technician, depending on the education program you choose. In fact, most pharmacy certification programs can be in a year, or less than eight months.

What is the net charge of C

Answers

Explanation:

Sorry, I don't know, but I can tell you that when an atom, or a body, has the same amount of positive charges (protons) and negative charges (electrons), it is said to be electrically neutral. ... The net charge corresponds to the algebraic sum of all the charges that a body possesses.

Answer: Neutral carbon-12 (or any carbon atom) has 6 electrons with a total negative charge of 6e- orbiting a nucleus with a total positive charge of 6e+, so that the total net charge is zero. The nucleus is made up of 6 protons, each with a positive charge of e+, and 6 neutrons, each with zero charge.

Explanation:

Which of the following elements would be a +2 cation?
Vanadium (V)
Oxygen (0)
Helium (He)
Strontium (Sr)

Answers

Answer:

helium

Explanation:

Someone please help me :)))

Answers

Answer:

3. solids are measured in centimeters

4. gases And liquids are measured in milliliters

Answer:

Solids are measured in Mass

Gases and Liquids are measured in Volume

Explanation:

Solids can also additionally be measured by length as well.

fun fact: natural gas is measured by volume (cubic feet) but is sold based on its heating content (Btus). A cubic foot of natural gas is the amount of natural gas that can be contained in a cube one foot on a side, at a certain standard temperature and pressure. (source; oilgaslawyer blog)

What are the steps to Photosynthesis

Answers

Answer:

Step 1-Light Dependent. CO2 and H2O enter the leaf.

Step 2- Light Dependent. Light hits the pigment in the membrane of a thylakoid, splitting the H2O into O2.

Step 3- Light Dependent. ...

Step 4-Light Dependent.

Step 5-Light independent.

Step 6-Light independent.

Which stage of a fire can be described as follows: The flames are not visible and the combustible item no longer generates heat or combustion products

Answers

Fire extinguishment is referred to the stage in which flames are not visible

and the combustible item no longer generates heat.

This stage refers to when the fire has been put out through a fire

extinguisher or other compounds.   When fire is put out, there is no longer

flames present.

The absence of flames also means that there is no heat generation or

combustion products due to the absence of a heat source.

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Identify the major product that is obtained when 1-hexyne is treated with H2 and Pd. cis-2-hexene 1-hexene hexane trans-2-hexene

Answers

The major product obtained when 1-hexyne is treated with H2 and Pd is; 1-hexene.

The structure of 1-hexyne is such that it possesses a triple bond around its first Carbon in it's carbon chain.

On this note; hydrogenation by treatment with H2 and Paladium, Pd as catalyst yields 1-hexene as the major product.

PS: Paladium, Pd is the major constituent of the Lindlar's catalyst.

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A gas has a pressure of 8.5atm and occupies 24L at 25∘C. What volume (in liters) will the gas occupy if the pressure is increased to 13.5atm and the temperature is decreased to 15∘C? Round to the nearest liter.

Answers

The volume (in liters) that the gas will occupy if the pressure is increased to 13.5 atm and the temperature is decreased to 15 °C is 15 L

From the question given above, the following data were obtained:

Initial pressure (P₁) = 8.5 atm

Initial volume (V₁) = 24 L

Initial temperature (T₁) = 25 °C = 25 + 273 = 298 K

Final pressure (P₂) = 13.5 atm

Final temperature (T₂) = 15 °C = 15 + 273 = 288 K

Final volume (V₂) =?

The final volume of the gas can be obtained by using the combined gas equation as illustrated below:

[tex]\frac{P_{1}V_{1}}{T_{1}} = \frac{P_{2}V_{2}}{T_{2}}\\\\\frac{8.5 * 24}{298} = \frac{13.5 * V_{2}}{288}\\\\ \frac{204}{298} = \frac{13.5 * V_{2}}{288}\\\\[/tex]

Cross multiply

298 × 13.5 × V₂ = 204 × 288

4023 × V₂ = 58752

Divide both side by 4023

[tex]V_{2} = \frac{58752}{4023}\\\\[/tex]

V₂ = 15 L

Therefore, the final volume of the gas is 15 L

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There are two unknowns in this problem - the mass of potassium carbonates and the mass of sodium carbonate. Let's designate the grams of potassium carbonate as our first unknown (you may want to call it gKcarb, or x, some other variable name that makes sense to you) and the grams of sodium carbonate as our second unknown(you may want to call it gNacarb, or y, some other variable name that makes sense to you). Set up an equation for the sum of your two unknowns. Starting with 'unknown' grams of potassium carbonate, use stoichiometry to calculate the number of moles of nitric acid that would react with the potassium carbonate. Your answer will have a variable for your unknown grams of potassium carbonate in it. Starting with 'unknown' grams of sodium carbonate, use stoichiometry to calculate the number of moles of nitric acid that would react with the sodium carbonate. Your answer will have a variable for your unknown grams of sodium carbonate in it. Set up an equation for what you get if you add these two quantities.

Answers

This problem, is describing two scenarios, the first one, a reaction between potassium carbonate and nitric acid, and also this very same acid with sodium carbonate. In addition, it is asked to set up two equations whereby you can get the grams of nitric acid needed to react with the unknown grams of both carbonates.

In this case, we can start off by designating the unknown mass of potassium carbonate as X and that of sodium carbonate as Y, so that we will be able to provide a reliable answer. Next, we write the corresponding chemical equations that take place:

K2CO3 + 2HNO3 --> 2KNO3 + H2O + CO2

Na2CO3 + 2HNO3 --> 2NaNO3 + H2O + CO2

After that, we can set up the conversion by considering the following calcultion track:

g Carbonate --> mol Carbonate --> mol HNO3 --> g HNO3

The conversion from grams to moles involve the carbonates' molar mass and the conversion from moles of nitric acid to grams, its molar mass well. In addition, we need the 1:2 mole ratio of the carbonates to nitric acid that it is evidenced in the reaction.

Therefore, the resulting equations that can be set up are shown as follows:

[tex]X g K_2CO_3 *\frac{1mol K_2CO_3 }{138.2 gK_2CO_3 } \frac{2molHNO_3}{1molK_2CO_3 } *\frac{63.1gHNO_3}{1molHNO_3} \\\\Y g Na_2CO_3 *\frac{1mol K_2CO_3 }{105.99 gK_2CO_3 } \frac{2molHNO_3}{1molNa_2CO_3 } *\frac{63.1gHNO_3}{1molHNO_3}[/tex]

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Calculate the number of molecules present in 11 moles of H2O.

Answers

Answer:

[tex]11 \times 6.022 \times {10}^{23} \\ = 66.242\times {10}^{23} \: of \: \\ water \: molecules[/tex]

2. Why do you think electroplated jewelleries are in demand?
Chemistry plsss

Answers

Explanation:

Electroplated jeweleries are in demand because firstly they are as shiny and attractive as real jeweleries, they are also light weighted and cost effective.

A local water retention pond was found to have elevated mass concentration of mercury of 14 ng per liter. You would like to collect some mercury for your homemade perpetuum mobile machine. How many moles of mercury can you get you collect and process the entire volume of 1250 m3 of the water in the pond?

Answers

The number of moles of mercury can you get you collect and process the entire volume of 1250 m3 of the water in the pond is 8.7  × 10^-5 moles.

First, we must convert the concentration of mercury in the pond to molar concentration using the relation;

Mass concentration = Molar concentration × molar mass

Molar concentration = Mass concentration /molar mass

Molar mass of mercury = 201 g/mol

Molar concentration = 14 × 10^-9 g/201 g/mol = 6.97 × 10^-11 M

Volume of solution = 1250 m3 or 1250000 L

Number of moles = concentration × volume

Number of moles =  6.97 × 10^-11 M ×  1250000 L

Number of moles = 8.7  × 10^-5 moles

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In chemical reactions, _______ always involves the release of energy during the reaction process.

a) the breaking of bonds
b) the formation of bonds
c) the addition of a catalyst
d) overcoming activation energy

Answers

Answer:

a. the breaking of bonds

Answer:

B

Explanation:

Hey, I am almost positive that the answer to this question is B. The breaking of bonds uses the energy but when they are created it releases energy. I hope this helps, Have a good day!

solvent extraction explain ???​

Answers

Answer:

this the partial removal of a substance from a solution or mixture by dissolving it in another immiscible solvent in which it is more soluble.

Radio waves bounce off of _____________ before returning to Earth

Answers

Answer:   ionosphere

Explanation:       First it bounces off a top layer of the atmosphere called the ionosphere, then it bounces back to the Earth (this is reflection. It then bounces up again to the ionosphere, and continues bouncing back again until it reaches the radio receiver. This is called a skywave, which works around 3 to 30 MHz.

Cómo se forma un enlace polipeptido?

Answers

Qué es la pregunta que estás preguntando?

Brainliest fast before 5:35 no link no bot

Answers

Answer:

1.) 7

2.) 5

3.) stable

4.) 5A

5.) 5

6.) The properties would be more stable to property of phosphorous because same group and valenve electronics and they also have same chemical

Explanation:

The rest i dont know

The EPA has used the slogan “Ozone: good up high, bad nearby” in some of its publications for the general public. Explain the message

Answers

Answer:

------------------------------

Explanation:

---------------

formula of sodium bicarbonate​

Answers

Answer:

NaHCO3

Explanation:

The three is small at the bottom at the end

Bas +
PtF2 →
BaF2 +
Pts
Need to balance it

Answers

it is already balanced

REACTANTS

Barium sulfide (BaS) + platinum (Ii) fluoride

PRODUCT

Barium fluoride (BaF2) + Cooperite (PtS)

Hope this answer helps you dear! take care

If you have an aqueous solution that is 13.5 % Na3PO4 by mass, what is the molality of Na3PO4 in the solution?

Answers

Considering the definition of percentage by mass and molality, the molality of Na₃PO₄ in the solution is 0.948 [tex]\frac{moles}{kg}[/tex].

Percentage by mass

The percentage by mass expresses the concentration and indicates the amount of mass of solute present in 100 grams of solution.

In other words, the percentage by mass of a component of the solution is defined as the ratio of the mass of the solute to the mass of the solution, expressed as a percentage.

The percentage by mass is calculated as the mass of the solute divided by the mass of the solution, the result of which is multiplied by 100 to give a percentage. This is:

[tex]percentage by mass=\frac{mass of solute}{mass of solution}x100[/tex]

Molality

Molality is the ratio of the number of moles of any dissolved solute to kilograms of solvent.

The Molality of a solution is determined by the expression:

[tex]molality=\frac{number of moles of solute}{kilograms of solvent}[/tex]

This case

Considering 100 grams as a sample of the solution, then the value of the percentage of concentration given indicates that  13.5 g correspond to Na₃PO₄.

Remember that percent concentration by mass is calculated using the mass of solute and the mass of the solution, which includes both the solute and the solvent. Then:

mass solution= mass solute + mass solvent

100 g= 13.5 g + mass solvent

100 g - 13.5 g= mass solvent

86.5 g= mass solvent

Then, you know:

number of moles of solvent=  [tex]13.5 gramsx\frac{1 mole}{163.94 grams} =0.082 moles[/tex] being 163.94 [tex]\frac{grams}{mole}[/tex]the molar mass of Na₃PO₄, this is the amount of mass a substance contains in one mole.mass of solvent= 86.5 grams= 0.0865 kg (being 1000 g= 1 kg)

Then, replacing in the definition of molality:

[tex]molality=\frac{0.082 moles}{0.0865 kg}[/tex]

Solving:

molality= 0.948 [tex]\frac{moles}{kg}[/tex]

Finally, the molality of Na₃PO₄ in the solution is 0.948 [tex]\frac{moles}{kg}[/tex].

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Can KI+Cl2 occur or not

Answers

Yes according to reliable sources.

What does a chemical reaction tell us?

Answers

Answer:

A chemical reaction rearranges the constituent atoms of the reactants to create different substances as products. The properties of the products are different from those of the reactants.

I hope this helps.

*1. The internal energy with a system associated with the motion of particles and that can be added to a substance is called_____.


A. Thermal energy


B. Electrostatic forces


C. Temperature


D. Kinetic energy










*2. Which statement describes the effect of adding more energy to a system, assuming a phase change does not occur?


A. The particles within the system will have greater motion, and the temperature will decrease.


B. The particles within the system will have greater motion, and the temperature will increase.


C. The particles within the system will have less motion, and the temperature will increase.


D. The particles within the system will have less motion, and the temperature will decrease.










*3. Which statement correctly describes how attractions that hold particles break?


A. Attractions due to electrostatic forces. When particles have low enough energy, these forces can no longer keep particles together.


B. Attractions due to gravitational forces. When particles have low enough energy, these forces can no longer keep particles together.


C. Attractions due to gravitational forces. When particles move fast enough, these forces can no longer keep particles together.


D. Attractions due to electrostatic forces. When particles move fast enough, these forces can no longer keep particles together.










*4. Which statement explains why a rubber band analogy is not a perfect comparison for bonds in a substance when considering phase changes?


A. For a phase change from liquid to gas, the bonds break completely and particles can move independently of each other.


B. For a phase change from liquid to gas, the bonds do not break completely and the particles can still slide past each other.


C. For a phase change from solid to liquid, the bonds break completely and particles can move independently of each other.


D. For a phase change from solid to liquid, the bonds do not break completely in the particles can still slide past each other.










*5. The boiling point of benzene is 80°C. Which pair of samples will have the same average kinetic energy as benzene molecules?


A. Two samples of liquid benzene, one at 70°C in the other at 80°C.


B. A sample of liquid benzene at 70°C and a sample of gaseous benzene at 90°C.


C. Two samples of gaseous benzene, one at 80°C in the other at 90°C.


D. A sample of liquid benzene at 80°C and a sample of gaseous benzene at 80°C.

Answers

Answer:

1. A/Thermal Energy

2. B/The particles within the system will have greater motion, and the temperature will increase.

3. C/Attractions occur due to electrostatic forces. When particles move fast enough, these forces can no longer keep particles together.

4. D/ For a phase change from solid to liquid, the bonds do not break completely and particles can still slide past each other.

5. D/ a sample of liquid benzene at 80ºC and a sample of gaseous benzene at 80ºC

Explanation:

I took the Test.

1. Internal energy associated with systems and particles is thermal energy. Thus, option A is correct.

The internal energy has been described as the energy that has been assessed by the molecules and bonds at the STP. Thermal energy has been the energy of particular molecules and the system comprising all the molecules have the summation of the thermal energy.

Thus, internal energy associated with systems and particles is thermal energy. Thus, option A is correct.

2. The addition of energy results in greater motion with an increase in temperature has been representation no phase change. Thus, option B is correct.

The addition of energy to the substance results in the increased motion of the particles. The energy higher than the threshold energy has been responsible for the phase change of the substance.

The addition of energy results in greater motion with an increase in temperature has been representation no phase change. Thus, option B is correct.

3. The movement of the particles under the gravitational attraction is not enough to hold the particles together at a longer distance. Thus, option B is correct.

The attraction has been the force that has been responsible for holding the particles in a molecule. Different attractions have a different levels of stability and strength.

The movement of the particles under the gravitational attraction is not enough to hold the particles together at a longer distance. Thus, option B is correct.

4. The phase change of the molecules has been mediated by overcoming the force of attraction that allows the molecules to move freely. The solid to liquid phase change has been mediated with the breaking of the attraction between the bonds allowing free movement.

Thus, statement 4 is incorrect, and option D is correct.

5. The kinetic energy has been the energy possessed by the moving molecules in the medium. The molecules in liquid and gas have been possessing the same energy at the same temperature, Thus, option D is correct.

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Pleeeeasee someone who’s good at chemistry?! 10 grade

ASAP
I’ll give points, just help please

Answers

Answer:

where is the question????????????

Explain why caesium is more reactive than sodium.
You should answer in terms of electrons.

Answers

Caesium is more reactive than sodium because when it is burned sodium will smell, taste, and look like poop

How many grams of steam at 100 °C would be required to raise the temperature
of 47.6 g solid benzene (CH) from 5.5 °C to 30.0 °C? Assume that heat is only
transferred from the steam (and not liquid water) and that the steam/water and
benzene are separated by a glass wall and do not mix. (The melting point of ben-
zene is 5.5 °C; AHus for benzene is 9.87 kJ/mol; specific heat for benzene is 1.63
J/g• °C; AH for steam at 100 °C is 40.7 kJ/mol.)
vap

Answers

The mass of steam required to raise the temperature of water is 3.5 g.

The given parameters;

mass of the benzene, = 47.6initial temperature of the benzene, = 5.5 ⁰Cfinal temperature of the benzene = 30 ⁰C

The molar mass of Benzene = 78.11 g/mol

The molar mass of water = 18 g/mol

The number of moles of the Benzene is calculated as follows;

[tex]n = \frac{47.6}{78.11} = 0.61 \ mole[/tex]

The mass of steam required is calculated as follows;

heat lost by steam = heat absorbed by benzene

[tex]\frac{m}{18} \times 40.7 \times 10^3 = 47.6(1.63)(30-5.5) \ + \ 0.61 \times 9.87 \times 10^3\\\\2261.11 m = 7921.61\\\\m = \frac{7921.61}{2261.11} \\\\m = 3.5 \ g[/tex]

Thus, the mass of steam required to raise the temperature of water is 3.5 g.

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