we need to use the balanced chemical equation for the decomposition of SbCl5: Therefore, you need to add 0.05955 moles of chlorine gas to the 15.00L container to make the new equilibrium concentration of SbCl3 (g) half that of the original equilibrium concentration.
SbCl5 (g) ⇌ SbCl3 (g) + Cl2 (g)
equilibrium concentrations given are:
[SbCl5] = 0.0293 M
[SbCl3] = [Cl2] = 0.00794 M
We want to find the number of moles of Cl2 that must be added to the container to make the new equilibrium concentration of SbCl3 to be half that of the original equilibrium concentration.
Let's call the new equilibrium concentration of SbCl3 "x" M. Since the volume of the container is constant at 15.00 L, we can use the equilibrium expression to set up an equation and solve for x:
Kc = [SbCl3][Cl2]/[SbCl5]
Kc = (0.00794)(0.00794)/(0.0293) = 0.001706 M
0.001706 = x(0.00794-x)/(0.0293+x)
Simplifying this equation and solving for x, we get:
x = 0.002296 M
This is half of the original equilibrium concentration of SbCl3, which was 0.00794 M. So, we need to add enough Cl2 to increase the concentration from 0.00794 M to 0.002296 M.
The change in concentration of Cl2 is:
Δ[Cl2] = x - [Cl2] = 0.002296 - 0.00794 = -0.005644 M
This means we need to remove 0.005644 M of Cl2 from the container. Since the volume of the container is 15.00 L, we can use the equation:
moles = concentration × volume
to calculate the number of moles of Cl2 that must be removed:
moles of Cl2 = (0.005644 M) × (15.00 L) = 0.08466 moles
Therefore, we need to remove 0.08466 moles of Cl2 from the container to reach the new equilibrium concentration of SbCl3.
To determine the number of moles of chlorine gas that must be added to the 15.00L container to make the new equilibrium concentration of SbCl3 (g) half that of the original equilibrium concentration, follow these steps:
1. Write the balanced equation for the reaction:
SbCl5 (g) ⇌ SbCl3 (g) + Cl2 (g)
2. Given the original equilibrium concentrations:
[SbCl5] = 0.0293 M
[SbCl3] = [Cl2] = 0.00794 M
3. The new equilibrium concentration of SbCl3 (g) should be half the original:
[SbCl3_new] = 0.5 * 0.00794 M = 0.00397 M
4. Since the stoichiometry of SbCl3 and Cl2 in the balanced equation is 1:1, the change in the concentration of Cl2 must be equal to the change in the concentration of SbCl3:
Δ[Cl2] = 0.00397 M
5. Calculate the number of moles of Cl2 to be added to the container:
moles of Cl2 = Δ[Cl2] * volume of container
moles of Cl2 = 0.00397 M * 15.00 L = 0.05955 moles
Therefore, you need to add 0.05955 moles of chlorine gas to the 15.00L container to make the new equilibrium concentration of SbCl3 (g) half that of the original equilibrium concentration.
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Calculate the ka of a weak acid ha if a 0.19 m aqueous solution of ha has a ph of 4.52 at 25°c.
The Ka of the weak acid HA at 25°C in a 0.19M aqueous solution is 0.0168.
The Ka of a weak acid HA can be calculated using the pH of the solution. The pH of a solution is a measure of the hydrogen ion concentration and is defined as the negative logarithm of the hydrogen ion concentration. At 25°C, a 0.19M aqueous solution of HA has a pH of 4.52.
To calculate the Ka, we must first calculate the hydrogen ion concentration. This can be done by taking the antilog of the negative pH (4.52) which is 0.0032. The Ka of HA can then be calculated as the ratio of the hydrogen ion concentration (0.0032) to the concentration of the acid (0.19). This gives us Ka = 0.0032/0.19 = 0.0168.
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suppose you start with one liter of vinegar and repeatedly remove 0.14 l, replace with water, mix, and repeat. a. find a formula for the concentration after steps. b. after how many steps does the mixture contain less than 14% vinegar?
The concentration of vinegar in the mixture after n steps can be found using the formula
Cn = (0.86)^n, where Cn is the concentration of vinegar after n steps.
To find the number of steps required to reach a concentration of less than 14%,
we need to solve the equation (0.86)^n = 0.14.
Taking the logarithm of both sides gives n = log(0.14)/log(0.86), which is approximately 14.1 steps.
Therefore, after 15 steps, the mixture will contain less than 14% vinegar.
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how much heat is produced in burning 2 mol of ch4 inder stnadard conditions if reactants and prodcuts ar brought to 298 K and H2O(l) is formed?
496.8 kJ mol⁻¹ heat is produced in burning 2 mol of CH₄ inter standard conditions if reactants and products are brought to 298 K and H2O(l) is formed.
The balanced chemical equation for the burning of CH₄ (methane) is:
CH₄(g) + 2O₂(g) ⇔ CO₂(g) + 2H₂O(l)
According to the equation, for every 1 mol of CH₄ that is burned, 2 mol of H₂O(l) is formed. Therefore, if 2 mol of CH₄ is burned, 4 mol of H₂O(l) is formed.
To calculate the amount of heat produced in the reaction, we need to use the standard enthalpy of formation values for the reactants and products. The standard enthalpy of formation is the change in Hess's Law that occurs when 1 mol of a substance is formed from its elements in their standard states at a specified temperature and pressure (usually 298 K and 1 atm).
Using the standard enthalpy of formation values, we can calculate the heat of reaction (ΔHrxn) using the following equation:
ΔHrxn = ∑nΔHf(products) - ΣnΔHf(reactants)
where ΣnΔHf is the sum of the standard enthalpies of formation for the products and reactants, respectively, and n is the stoichiometric coefficient for each substance in the balanced equation.
For the reaction given, the standard enthalpy of formation values are:
ΔHf(CH₄) = -74.8 kJ mol⁻¹
ΔHf(O₂) = 0 kJ mol⁻¹
ΔHf(CO₂) = -393.5 kJ mol⁻¹
ΔHf(H₂O) = -285.8 kJ mol⁻¹
Substituting these values into the equation, we get:
ΔHrxn = [2(-285.8 kJ mol⁻¹)] - [(-74.8 kJ mol⁻¹) + 2(0 kJ mol⁻¹)]
= -571.6 kJ mol⁻¹ - (-74.8 kJ mol⁻¹)
ΔHrxn = -496.8 kJ mol⁻¹
This means that for every 2 mol of CH₄ that is burned, 496.8 kJ of heat is produced. Since the reaction is carried out at standard conditions (298 K and 1 atm), the heat produced is equal to the change in enthalpy (ΔH) of the reaction. Therefore, if 2 mol of CH₄ is burned, 496.8 kJ mol⁻¹ of heat is produced.
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496.8 kJ mol⁻¹ heat is produced in burning 2 mol of CH₄ inter standard conditions if reactants and products are brought to 298 K and H2O(l) is formed.
The balanced chemical equation for the burning of CH₄ (methane) is:
CH₄(g) + 2O₂(g) ⇔ CO₂(g) + 2H₂O(l)
According to the equation, for every 1 mol of CH₄ that is burned, 2 mol of H₂O(l) is formed. Therefore, if 2 mol of CH₄ is burned, 4 mol of H₂O(l) is formed.
To calculate the amount of heat produced in the reaction, we need to use the standard enthalpy of formation values for the reactants and products. The standard enthalpy of formation is the change in Hess's Law that occurs when 1 mol of a substance is formed from its elements in their standard states at a specified temperature and pressure (usually 298 K and 1 atm).
Using the standard enthalpy of formation values, we can calculate the heat of reaction (ΔHrxn) using the following equation:
ΔHrxn = ∑nΔHf(products) - ΣnΔHf(reactants)
where ΣnΔHf is the sum of the standard enthalpies of formation for the products and reactants, respectively, and n is the stoichiometric coefficient for each substance in the balanced equation.
For the reaction given, the standard enthalpy of formation values are:
ΔHf(CH₄) = -74.8 kJ mol⁻¹
ΔHf(O₂) = 0 kJ mol⁻¹
ΔHf(CO₂) = -393.5 kJ mol⁻¹
ΔHf(H₂O) = -285.8 kJ mol⁻¹
Substituting these values into the equation, we get:
ΔHrxn = [2(-285.8 kJ mol⁻¹)] - [(-74.8 kJ mol⁻¹) + 2(0 kJ mol⁻¹)]
= -571.6 kJ mol⁻¹ - (-74.8 kJ mol⁻¹)
ΔHrxn = -496.8 kJ mol⁻¹
This means that for every 2 mol of CH₄ that is burned, 496.8 kJ of heat is produced. Since the reaction is carried out at standard conditions (298 K and 1 atm), the heat produced is equal to the change in enthalpy (ΔH) of the reaction. Therefore, if 2 mol of CH₄ is burned, 496.8 kJ mol⁻¹ of heat is produced.
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onsider the following reaction occurring at 298 K: CaCO3(s) = CaO(s) + CO2(g) The following table shows standard thermodynamic quantities for each product and reactant at 298 K. Substance AH; (kJ/mol) AG; (kJ/mol) Sº (J/mol · K) CaCO3(s) - 1207.6 - 1129.1 91.7 CaO(s) -634.9 -603.3 38.1 CO2(g) -393.5 --394.4 213.8 Show that the reaction is not spontaneous under standard conditions by calculating A Grxn. Use the AG; values from the given table. Express your answer in kilojoules to one decimal place. 「 VO ΑΣΦ ? AGPxn kJ Submit Previous Answers Request Answer If CaCO3 is placed in an evacuated flask, what partial pressure of CO2 will be present when the reaction reaches equilibrium? Express your answer in atmospheres to three significant figures. V AED ? P = atm Submit Request Answer Part C Can the reaction be made more spontaneous by an increase or decrease in temperature?
To calculate the A GPxn, we can use the formula A GPxn = ΣA G°f(products) - ΣA G°f(reactants), where A G°f is the standard free energy of formation.
Plugging in the values from the table, we get:
A GPxn = (-603.3 kJ/mol + (-394.4 kJ/mol)) - (-1129.1 kJ/mol)
A GPxn = -8.6 kJ/mol
Since A Grxn is negative, the reaction would be spontaneous under standard conditions. However, since A GPxn is only slightly negative (-8.6 kJ/mol), the reaction would not proceed to completion without some external driving force.
If CaCO3 is placed in an evacuated flask, the partial pressure of CO2 at equilibrium can be calculated using the equilibrium constant, Kp. The equilibrium constant can be expressed as:
Kp = (P CO2)^x, where x is the coefficient of CO2 in the balanced equation (1 in this case)
We can then use the formula A Grxn = -RT ln Kp to solve for P CO2:
A GPxn = -RT ln Kp
-8.6 kJ/mol = -(8.314 J/mol·K)(298 K) ln(P CO2)
ln(P CO2) = 3.307
P CO2 = e^3.307 = 27.3 atm
Therefore, the partial pressure of CO2 at equilibrium would be 27.3 atm.
The spontaneity of the reaction can be affected by a change in temperature. We can use the equation A GPxn = A Hrxn - TΔSrxn to see how the free energy change varies with temperature. If we increase the temperature, the TΔSPxn term becomes more favorable (i.e. more positive), which can offset the positive A Hrxn term, resulting in a more negative A GPxn and a more spontaneous reaction.
Therefore, increasing the temperature can make the reaction more spontaneous. On the other hand, decreasing the temperature can make the reaction less spontaneous.
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Determine the mechanism of nucleophilic substitution of the reaction and draw the products, including stereochemistry. The reaction proceeds by which mechanism?
a. SN1
b. SN2
[tex]SN_{2}[/tex]is the mechanism of the reaction's nucleophilic substitution and the products' stereochemistry.
With an example, what is a nucleophile?
A nucleophile is just a reactant that contributes a two electrons to the formation of a covalent bond. A nucleophile is typically negatively charged or neutral, with a single pair of donatable electrons. Examples include [tex]H_{2} O[/tex] -OMe, and -OtBu.
What are some examples of nucleophiles and electrophiles?
Electrophiles are electron-deficient organisms that could accept a two electrons from an electron-rich organism. Carbocations and alkenes are two examples. A nucleophile is an electron-rich organism that wants to donate electron pairs to electron-deficient organisms. Carbanions, water, ammonia, cyanide ion, and other examples are given.
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Calculate the pH of a solution containing an amphetamine concentration of 245 mg/Amphetamine (C9H13N) is a weak base with a pKb of 4.2.
The pH of the solution containing 245 mg/L of amphetamine is approximately 9.87.
The pH of the solution containing 245 mg/L of amphetamine (C₉H₁₃N) can be calculated using the following steps:
Convert the concentration of amphetamine from mg/L to mol/L:
245 mg/L ÷ 135.21 g/mol =[tex]1.811 * 10^{-3[/tex] mol/L
Calculate the concentration of hydroxide ions ([OH⁻]) using the base dissociation constant (Kb):
Kb = [BH⁺][OH⁻]/[B][tex]10^{-pKb[/tex] = [OH⁻][B]/[BH⁺][tex]10^{-4.2[/tex] = [OH⁻]²/([C₉H₁₃N][H₂O])Assuming that [OH⁻] << [C₉H₁₃N], the equation simplifies to:
[OH⁻] ≈ √(Kb[C₉H₁₃N]) = √(2.51 × 10⁻⁵ × 1.811 × 10⁻³) = 7.43 × 10⁻⁵ mol/LCalculate the concentration of hydrogen ions ([H+]) using the equation:
Kw = [H⁺][OH⁻]
10⁻¹⁴ = [H⁺][7.43 × 10⁻⁵]
[H⁺] = 1.35 × 10⁻¹⁰ mol/L
Calculate the pH using the equation:
pH = -log[H⁺]
pH = -log(1.35 × 10⁻¹⁰) = 9.87
Therefore, the pH of the solution containing 245 mg/L of amphetamine is approximately 9.87. Since the pKb of amphetamine is relatively low, it behaves as a weak base and the resulting pH of the solution is basic.
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Determine [oh−][oh−] of a solution that is 0.230 mm in hco3−hco3−.
The [OH⁻][OH⁻] of a solution that is 0.230 mM in HCO₃⁻ can be calculated using the equilibrium expression for the bicarbonate ion.
The chemical equation for the dissociation of bicarbonate ion is:
HCO₃⁻ + H₂O ⇌ H₂CO₃ + OH⁻
The equilibrium constant expression for this reaction can be written as:
K = [H₂CO₃][OH⁻] / [HCO₃⁻]
Since the concentration of H₂CO₃ is negligible in this case, we can assume that [H₂CO₃] ≈ 0. Therefore, the equilibrium constant expression can be simplified as:
K = [OH⁻][HCO₃⁻]
We can rearrange this equation to solve for [OH⁻]:
[OH⁻] = K / [HCO₃⁻]
The equilibrium constant for this reaction (K) is 2.4 × 10⁻⁴ at 25°C.
Substituting the values given in the problem, we get:
[OH⁻] = (2.4 × 10⁻⁴) / 0.230 = 1.04 × 10⁻³ M
Therefore, the [OH⁻][OH⁻] of the solution is 1.04 × 10⁻⁶.
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calculate the concentration of i−i− in a solution obtained by shaking 0.16 mm kiki with an excess of agcl(s)agcl(s) .
The I- ion concentration in the solution produced by shaking 0.16 mM KI with an excess of AgCl(s) is 0.16 M.
How to determine ion concentration?The solubility product constant for AgCl is given by:
Ksp = [Ag+][Cl-] = 1.77 x 10⁻¹⁰
Since AgCl is an ionic solid, it dissociates in water to produce Ag+ and Cl- ions:
AgCl(s) ⇌ Ag+(aq) + Cl-(aq)
When AgCl is added to the KI solution, a precipitation reaction occurs:
Ag+(aq) + I-(aq) ⇌ AgI(s)
The Ksp expression for AgCl can be used to calculate the concentration of Ag+ ions produced when AgCl dissolves in the solution:
Ksp = [Ag+][Cl-] = [Ag+]([Ag+] + [I-])
Since AgCl is considered to be insoluble, the concentration of [Ag+] can be assumed to be very small and can be neglected in the expression. Therefore, the concentration of [I-] can be approximated to be equal to the concentration of [Cl-]:
Ksp = [Ag+][Cl-] = [Cl-]²
Solving for [Cl-]:
[Cl-] = √(Ksp) = √(1.77 x 10⁻¹⁰) = 1.33 x 10⁻⁵ M
Since the KI solution is a 0.16 M solution, the concentration of [I-] can be approximated to be 0.16 M (assuming that the solubility of KI is much greater than AgCl). Therefore, the concentration of [I2-] can be calculated using the following equation:
[I2-] = 2[Ag+] = 2[Cl-] = 2(1.33 x 10⁻⁵) = 2.66 x 10⁻⁵ M
Thus, the concentration of I- ions in the solution obtained by shaking 0.16 mM KI with an excess of AgCl(s) is 0.16 M.
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Calculate the potential of the electrochemical cell and determine if it is spontaneous as written at 25 ∘C . Cu(s) ∣∣ Cu2+(0.13 M) ‖‖ Fe2+(0.0013 M) ∣∣ Fe(s) ∘Cu2+/Cu=0.339 V∘Fe2+/Fe=−0.440 Vcell=Is the electrochemical cell spontaneous or not spontaneous as written at 25 ∘C ?
a. The potential of the electrochemical cell: Cu(s) ∣∣ Cu₂⁺(0.13 M) ‖‖ Fe₂⁺(0.0013 M) ∣∣ Fe(s) as written at 25 ∘C is 0.3094 V.
b. The electrochemical cell is spontaneous as written at 25 ∘C.
To calculate the potential of the electrochemical cell, we can use the formula:
Ecell = E°cell - (0.0592/n) log(Q)
where E°cell is the standard potential of the cell, n is the number of electrons transferred, and Q is the reaction quotient.
For the given electrochemical cell:
Cu(s) ∣∣ Cu₂⁺(0.13 M) ‖‖ Fe₂⁺(0.0013 M) ∣∣ Fe(s)
The number of electrons transferred is 2 (from Cu to Fe).
The reaction quotient can be calculated using the concentrations of the species involved:
Q = ([Fe₂⁺]/[Cu₂⁺])
= (0.0013)/(0.13)
= 0.01
Substituting the values:
Ecell = 0.339 V - (0.0592/2) log(0.01)
Ecell = 0.339 V - 0.0296 = 0.3094 V
Since the potential of the electrochemical cell is positive (0.3094 V), the cell reaction is spontaneous as written at 25 ∘C.
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Consider the following equilibrium system in a closed vessel. N2O4 is a colourless gas while NO2 is red/brown gas.
N204 (g) ⇌ 2 NO2 (g) AH = +57.2 kJ/mol
Predict what will happen to the colour of the gas mixture in the vessel (lighten, darken) if :
a) More N204 is added to the vessel
b) The volume of the vessel is increased
c) The system is cooled down
The colour of the gas mixture in the vessel will darken if more N₂O₄ is added to the vessel, if the volume of the vessel is increased, and if the system is cooled down.
The given reaction is an endothermic reaction as indicated by the positive enthalpy change. When N₂O₄ is heated, it decomposes into NO₂ gas which is red/brown in colour. On the other hand, when NO₂ gas is cooled down or the pressure is increased, it forms N₂O₄ which is a colourless gas. Therefore, when the equilibrium shifts towards the reactants, the gas mixture in the vessel will lighten, and when the equilibrium shifts towards the products, the gas mixture will darken.
(a) If more N₂O₄ is added to the vessel, the concentration of N₂O₄ will increase, causing the equilibrium to shift towards the products to maintain equilibrium. Thus, the gas mixture in the vessel will darken due to the increased concentration of NO₂ gas.
(b) If the volume of the vessel is increased, the equilibrium will shift towards the side with more moles of gas to maintain equilibrium. In this case, the volume is increased on the reactant side, where there is only one mole of gas, while there are two moles of gas on the product side. Thus, the equilibrium will shift towards the products, resulting in the gas mixture in the vessel darkening.
(c) If the system is cooled down, the equilibrium will shift towards the side that produces heat. In this case, since the reaction is endothermic, the equilibrium will shift towards the reactants, resulting in the gas mixture in the vessel lightening as the concentration of NO₂ gas decreases.
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A firkin is an old British unit of volume. How many firkins are there in 825 in3? Some equality statements which may be helpful are: 1 barrel = 4 firkins (exact) 1 gallon = 231.0 in3 1 gallon = 3.78 L 1 barrel = 42.0 gallons.
There are approximately 0.34 firkins in 825 in³.
To find how many firkins are in 825 in³, we need to follow these steps:
1. Convert 825 in³ to gallons using the conversion factor 1 gallon = 231.0 in³.
2. Convert the gallons to barrels using the conversion factor 1 barrel = 42.0 gallons.
3. Convert the barrels to firkins using the conversion factor 1 barrel = 4 firkins.
Step 1: Convert 825 in³ to gallons:
825 in³ * (1 gallon / 231.0 in³) = 3.57 gallons (approximately)
Step 2: Convert 3.57 gallons to barrels:
3.57 gallons * (1 barrel / 42.0 gallons) = 0.085 barrels (approximately)
Step 3: Convert 0.085 barrels to firkins:
0.085 barrels * (4 firkins / 1 barrel) = 0.34 firkins (approximately)
So, there are approximately 0.34 firkins in 825 in³.
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draw any necessary curved arrows to show the reaction between the ketone and hydronium ion.
The reaction between the ketone and hydronium ion is given below which is known as Carbonyl Addition.
A bond-forming or bond-breaking step normally occurs during an elementary reaction. A pair of electrons are transferred from one atom to another during the bond-forming process. A pair of electrons that were formerly shared by two atoms are pulled to one end of the bond or the other during a bond-breaking phase, causing the bond to break and the electrons to land on only one atom.
Oxygen on Carbonyl group attacks Hydronium group protons with one of its lone pairs ==> it results in aldehyde protonated at Oxygen with +1 charge and one lone pair and water molecule (H₂O) with 2 lone pairs.
Depending on whether the molecules are under acidic or basic conditions, these reactions can really happen in a few distinct ways. There are more protons circulating about in acidic circumstances. Protons like to adhere to objects that have lone pairs to share, so they aren't entirely alone.
There aren't many additional protons present under normal circumstances. There might be nucleophilic species like hydroxide ions or others nearby. The compounds known as nucleophile species are those that donate electrons and are drawn to positive charges or electrophiles.
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How does the magnitude of Hmix compare with the magnitude of Hsolute+Hsolvent for exothermic solution processes?
A) The magnitude of Hmix will be larger than the magnitude of Hsolute+Hsolvent .
B) The magnitude of Hmix will be equal to the magnitude of Hsolute+Hsolvent .
C) The magnitude of Hmix will be smaller than the magnitude of Hsolute+Hsolvent
The magnitude of Hmix compared with the magnitude of Hsolute+Hsolvent for exothermic solution processes is Option C- The magnitude of Hmix will be smaller than the magnitude of Hsolute+Hsolvent,
For exothermic solution processes, the overall enthalpy change is negative (i.e. heat is released). The enthalpy change for mixing (Hmix) is typically negative for an ideal solution, meaning that energy is released when the solute and solvent are mixed together.
The enthalpy change for solvation (Hsolute+Hsolvent) is also negative, as energy is released when the solute particles interact with the solvent particles. Since both Hmix and Hsolute+Hsolvent are negative for exothermic solution processes, the magnitudes of the two enthalpy changes will be additive. Hence , option C is correct.
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How many grams of KOH are contained in 400. mL of 0.250 M KOH solution?
a) 8.98 g
b) 89.8 g
c) 35.1 g
d) 5.61 g
e) 12.4 g
The correct answer is (d) 5.61 g.
To calculate the grams of KOH in a 400 mL of 0.250 M KOH solution, we can follow the given steps:
Convert the volume from milliliters (mL) to liters (L): 400 mL = 0.4 L.
Use the molarity formula:
moles of solute = molarity × volume in liters.
Here, the molarity of the solution is given as 0.250 M, and the volume is 0.4 L.
moles of KOH = 0.250 M × 0.4 L = 0.1 moles.
Convert moles to grams using the molar mass of KOH (39.1 g/mol for K, 15.999 g/mol for O, and 1.008 g/mol for H):
The molar mass of KOH is (39.1 + 15.999 + 1.008) g/mol = 56.107 g/mol.
grams of KOH = 0.1 moles × 56.107 g/mol = 5.61 g.
Therefore, the grams of KOH in 400 mL of 0.250 M KOH solution is 5.61 g.
So, the correct answer is (d) 5.61 g.
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Sodium borohydride (NaBH4) is a very selective reagent. Which functional groups can sodium borohydride reduce? Choose all that apply.I. KetoneII. AldehydeIII. EsterIV. Carboxylic Acid
Sodium borohydride is a highly selective reagent that can reduce ketones, aldehydes, and esters, but cannot reduce carboxylic acids. Sodium borohydride (NaBH4) is a highly selective reagent that is commonly used as a reducing agent in organic chemistry. It is used to reduce various functional groups to their corresponding alcohols.
The functional groups that can be reduced by sodium borohydride include ketones, aldehydes, and esters. However, carboxylic acids cannot be reduced by sodium borohydride.
The reduction of ketones and aldehydes by sodium borohydride is a well-known reaction that is often used in synthetic organic chemistry. The reduction of these functional groups involves the transfer of a hydride ion (H-) from sodium borohydride to the carbonyl carbon, resulting in the formation of a new alcohol group.
Similarly, esters can also be reduced by sodium borohydride to form alcohols. However, the reduction of esters is slower than that of ketones and aldehydes due to the presence of the bulky ester group.
On the other hand, carboxylic acids cannot be reduced by sodium borohydride because they are already at their lowest oxidation state. Instead, carboxylic acids can be converted to their corresponding esters or amides, which can then be reduced by sodium borohydride.
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An unsaturated hydrocarbon (CsHs) undergoes Markovnikov's rule to give (A). Compound (A) is hydrolysed with aqueous alkali to yield (B). When (B) is treated with PBrs, compound (C) is produced. (C) reacts with AgCN (alc.) to give another compound (D). The compound (D) if reduced with LIA/H, produce (E).
An unsaturated hydrocarbon (CsHs) undergoes Markovnikov's rule to give (A). Compound (A) is hydrolysed with aqueous alkali to yield (B). When (B) is treated with PBrs, compound (C) is produced. (C) reacts with AgCN (alc.) to give another compound (D). The compound (D) if reduced with LIA/H, produce (E).
First, we know that the unsaturated hydrocarbon CsHs undergoes Markovnikov's rule. This means that the more electronegative atom will add to the carbon with the fewer hydrogen atoms. Based on this information, we can assume that compound A is a product of the addition of a proton and a more electronegative atom (such as a halogen or oxygen) to the unsaturated hydrocarbon.
Compound A is then hydrolyzed with aqueous alkali to yield compound B. This suggests that compound A contains a functional group that is susceptible to hydrolysis by base, such as an ester or an amide.
When compound B is treated with PBrs, compound C is produced. PBrs is a reagent used to test for the presence of halogens in a compound. This suggests that compound B contains a halogen, possibly added in the addition reaction with the unsaturated hydrocarbon.
Compound C reacts with AgCN (alc.) to give another compound, D. AgCN (alc.) is a reagent commonly used for the synthesis of nitriles from halides. This suggests that compound C contains a halogen atom that can be replaced by a cyano group (CN-) to form a nitrile.
Finally, compound D can be reduced with LIA/H to produce compound E. LIA/H is a reducing agent commonly used for the reduction of nitriles to primary amines. This suggests that compound D is a nitrile, which can be converted to a primary amine via reduction.
Hence, we can infer that the unsaturated hydrocarbon CsHs undergoes addition with a more electronegative atom according to Markovnikov's rule to form compound A. Compound A is then hydrolyzed to form compound B, which contains a halogen. Compound B is then converted to a nitrile (compound C) using PBrs, and compound C is converted to a primary amine (compound D) via reaction with AgCN (alc.) and subsequent reduction with LIA/H to produce compound E.
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express sp in terms of molar solubility, , for the salts with the given formulas.ab(s) sp= ab2(s) sp= ab3(s) sp= a3b2(s) sp=
Sp in terms of molar solubility for ab(s) is s², ab₂(s) is 4s₃, ab₃(s) is 27s⁴, and a₃b₂(s) is 108s⁵.
1. For AB(s):
Let the molar solubility of AB be 's'. When it dissolves, it forms A+ and B- ions. So the equilibrium concentrations are:
[A+] = s
[B-] = s
Ksp = [A+][B-] = (s)(s) = s²
2. For AB2(s):
Let the molar solubility of AB2 be 's'. When it dissolves, it forms A+ and 2B- ions. So the equilibrium concentrations are:
[A+] = s
[B-] = 2s
Ksp = [A+][B-]² = (s)(2s)² = 4s³
3. For AB3(s):
Let the molar solubility of AB3 be 's'. When it dissolves, it forms A+ and 3B- ions. So the equilibrium concentrations are:
[A+] = s
[B-] = 3s
Ksp = [A+][B-]³ = (s)(3s)³ = 27s⁴
4. For A3B2(s):
Let the molar solubility of A3B2 be 's'. When it dissolves, it forms 3A+ and 2B- ions. So the equilibrium concentrations
[A+] = 3s
[B-] = 2s
Ksp = [A+]^3[B-]² = (3s)³(2s)² = 108s⁵
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5. Imagine that we perform this ballistic pendulum experiment again, but we reverse the pendulum such that it no longer catches the ball. Instead, the ball hits the pendulum and bounces off.a. Would the energy transferred from the ball to the pendulum be greater or lesser than the energy transferred in your earlier trials? (3 pts) Hint: When we reverse the pendulum so that it cannot catch the ball, what type of collision is it?b. Would the angle that the pendulum swings be greater or lesser than the angle from your earlier trials? (2 pts)
In the modified ballistic pendulum experiment you described, the energy transferred from the ball to the pendulum would be lesser than in your earlier trials.
This is because when the ball bounces off the pendulum, it is an elastic collision, where some kinetic energy is retained by the ball after the collision, unlike the inelastic collision when the pendulum catches the ball.
a. If we reverse the pendulum such that it cannot catch the ball, the collision between the ball and the pendulum would be an elastic collision. In an elastic collision, the total kinetic energy of the system is conserved. Therefore, the energy transferred from the ball to the pendulum would be the same as in the earlier trials.
b. The angle that the pendulum swings would be greater than the angle from earlier trials. This is because in an elastic collision, the momentum of the system is conserved. Since the ball would bounce off the pendulum with the same speed at which it hit the pendulum, it would transfer more momentum to the pendulum. As a result, the pendulum would swing to a greater angle.
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sort the alkyl halide used to its substitution pattern:1-bromobutane primary 4 2-bromobutane secondary 2-bromo-2-methylbutane tertiary
So, the sorted alkyl halides based on their substitution pattern are: 1-bromobutane (primary), 2-bromobutane (secondary), and 2-bromo-2-methylbutane (tertiary).
What factors affect Alkyl Substitution?The given alkyl halides are 1-bromobutane (primary), 2-bromobutane (secondary), and 2-bromo-2-methylbutane (tertiary). Here's the sorting process:
1. Primary alkyl halide: 1-bromobutane
- This is a primary alkyl halide because the carbon atom bonded to the halogen (bromine) is attached to only one other carbon atom.
2. Secondary alkyl halide: 2-bromobutane
- This is a secondary alkyl halide because the carbon atom bonded to the halogen (bromine) is attached to two other carbon atoms.
3. Tertiary alkyl halide: 2-bromo-2-methylbutane
- This is a tertiary alkyl halide because the carbon atom bonded to the halogen (bromine) is attached to three other carbon atoms.
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Why does the carbonyl stretching frequency in the IR spectrum of camphor occur near 1740 cm-1 whereas that of acetophenone (C6H5COCH3) is found at 1680 cm-1 and that for cyclohexanone is found at 1710 cm-1?
The carbonyl stretching frequency in the IR spectrum of camphor occurs near 1740 cm-1, while that of acetophenone is found at 1680 cm-1 and cyclohexanone at 1710 cm-1, primarily due to differences in the electron density and the steric environment around the carbonyl group in these compounds.
In camphor, the carbonyl group is part of a rigid bicyclic structure, which results in less electron delocalization and reduced conjugation. This causes a higher carbonyl stretching frequency, as there is less stabilization of the carbonyl bond, leading to a value near 1740 cm-1.
In acetophenone, the carbonyl group is conjugated with the phenyl ring, which increases electron density around the carbonyl group and stabilizes the bond. This results in a lower stretching frequency, found at 1680 cm-1.
In cyclohexanone, the carbonyl group is in a less-conjugated environment compared to acetophenone but more so than in camphor, causing the stretching frequency to fall in between, at around 1710 cm-1.
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As shown in Table 8.1 why does citric acid have three pKa measurements listed, while malic acid has two lactic and acetic acids each have one?
Citric acid has three pKa measurements listed because it is a triprotic acid, meaning it has three acidic hydrogen atoms that can be donated as protons.
Malic acid has two pKa measurements since it is a diprotic acid with two acidic hydrogen atoms. Lactic and acetic acids each have one pKa measurement because they are both monoprotic acids, having only one acidic hydrogen atom to donate.
The pKa value of an acid indicates the strength of its acidic properties and the degree to which it can donate protons in solution. The number of pKa values for an acid corresponds to the number of dissociable hydrogen atoms it has, with each dissociation yielding a different pKa value. In general, acids with multiple pKa values are more complex than monoprotic acids and can undergo stepwise dissociation reactions.
Understanding the pKa values of different acids is important in various fields, including chemistry, biochemistry, and pharmacology, where it can affect the behavior of molecules and their interactions with other substances.
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What is the ph of a weak base with a concentration of 0.66m? kb=8.6*10^-10
The pH of the weak base with a concentration of 0.66 M and Kb value of 8.6 x 10⁻¹⁰ is 9.28.
To find the pH of a weak base, we first need to use the equilibrium constant expression for its reaction with water to calculate the hydroxide ion concentration.
The equilibrium constant expression for the reaction of a weak base, B, with water is:
Kb = [BH⁺][OH⁻] / [B]
Assuming that the initial concentration of the weak base is the same as its equilibrium concentration, we can write:
Kb = x² / (0.66 - x)
where x is the concentration of OH⁻ ions formed when the weak base dissociates.
Since the weak base is weak, we can assume that x is much smaller than 0.66, so we can simplify the equation:
Kb = x² / 0.66
Solving for x, we get:
x = √(Kb x 0.66) = √(8.6 x 10⁻¹⁰ x 0.66) = 1.9 x 10⁻⁵ M
Now, we can use the fact that pH + pOH = 14 to calculate the pH:
pOH = -log[OH⁻] = -log(1.9 x 10⁻⁵) = 4.72
pH = 14 - pOH = 9.28
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explain what is different about the molecules that provides a difference in your answers to questions 6 and 7. (hint: this has to do with the geometries around the various carbon atoms,)
In questions 6 and 7, we are comparing two different molecules that have the same molecular formula but different structures. Specifically, we are comparing cis-2-butene and trans-2-butene.
The difference between these two molecules lies in the geometry around the carbon-carbon double bond. In cis-2-butene, the two methyl groups (CH3) are on the same side of the double bond, while in trans-2-butene, the two methyl groups are on opposite sides of the double bond.
This difference in geometry leads to different physical and chemical properties of the two molecules, including differences in boiling point, melting point, reactivity, and stereochemistry. For example, cis-2-butene has a higher boiling point than trans-2-butene due to its greater polarity caused by the proximity of the two methyl groups on the same side. Additionally, the two isomers may react differently in certain chemical reactions due to differences in steric hindrance and orientation of functional groups relative to the double bond.
Therefore, the differences in the geometries of the carbon atoms in cis-2-butene and trans-2-butene are what provide a difference in the properties and reactivity of these molecules.
citric acid, a tricarboxylic acid important in intermediary metabolism, can be symbolized as h3a. its dissociation reactions are
H3A --> H+ + H2A pK1=3.13
H2A --> H+ + HA2- pK2=4.76
HA2- --> H+ + A3+ pK3=6.40 If the total concentration of the acid and its anion forms is 0.02 M, what are the individual concentrations of H3A, H2A, HA2, and A3 at pH 5.2?
The individual concentrations of H3A is 0.0057 M, H2A is 0.451 M, HA2- is 0.0143 M, and A3 is 0.0005 M at pH 5.2 when the total concentration of the acid and its anion forms is 0.02 M.
To find the individual concentrations of H3A, H2A, HA2, and A3 at pH 5.2, we need to use the Henderson-Hasselbalch equation, which relates the pH, pKa, and the concentrations of acid and its conjugate base.
First, let's calculate the ratio of [HA2-]/[H2A] using the pKa2 value and the pH:
pH = pKa2 + log([HA2-]/[H2A])
5.2 = 4.76 + log([HA2-]/[H2A])
log([HA2-]/[H2A]) = 0.44
[HA2-]/[H2A] = 10^0.44 = 2.51
Next, we can use the law of conservation of mass to write equations for the concentrations of each species in terms of x, the concentration of H3A:
[H3A] + [H2A] + [HA2-] + [A3+] = 0.02 M
[H3A] = x
[H2A] = x/(10^(pKa1-pH)) = x/(10^(3.13-5.2)) = 79.1x
[HA2-] = 2.51x
[A3+] = (0.02 M) - x - 79.1x - 2.51x
Now, we can substitute these expressions into the conservation of mass equation and solve for x:
x + 79.1x + 2.51x + (0.02 M) - x - 79.1x - 2.51x = 0.02 M
3.51x = 0.02 M
x = 0.0057 M
Therefore, the individual concentrations of H3A, H2A, HA2, and A3 at pH 5.2 are:
[H3A] = 0.0057 M
[H2A] = 0.451 M
[HA2-] = 0.0143 M
[A3+] = 0.0005 M
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If a non-cyclic alkane shows a molecular ion peak at m/z 492, what is the chemical formula?
Complete the formula:
CnHy
n=_____ carbon atoms
y=_____ hydrogen atoms
The molecular ion peak indicates the molecular weight of the compound. In this case, the non-cyclic alkane has a molecular weight of 492. To determine the chemical formula, we need to know the number of carbon and hydrogen atoms in the molecule.
The formula for a non-cyclic alkane is CnH2n+2. The "+2" represents the two additional hydrogen atoms needed to satisfy the valency of carbon.
To find the number of carbon atoms in the molecule, we can divide the molecular weight by the atomic weight of carbon (12.01). 492/12.01 ≈ 41.
Therefore, the chemical formula for this non-cyclic alkane is C41H84.
n= 41 carbon atoms
y= 84 hydrogen atoms.
A non-cyclic alkane, molecular ion peak, and chemical formula.
If a non-cyclic alkane shows a molecular ion peak at m/z 492, you can determine the chemical formula using the general formula for alkanes, which is CnH(2n+2).
Step 1: Use the given molar mass (492) to create an equation.
12n + (2n+2)(1) = 492
Step 2: Simplify the equation.
12n + 2n + 2 = 492
Step 3: Combine like terms.
14n + 2 = 492
Step 4: Subtract 2 from both sides.
14n = 490
Step 5: Divide by 14 to find the number of carbon atoms (n).
n = 490 / 14
n = 35 carbon atoms
Step 6: Calculate the number of hydrogen atoms (y) using the alkane formula.
y = 2n + 2
y = 2(35) + 2
y = 70 + 2
y = 72 hydrogen atoms
So, the chemical formula for the non-cyclic alkane with a molecular ion peak at m/z 492 is CnHy, where n=35 carbon atoms and y=72 hydrogen atoms. Your answer: C35H72
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calculate the ratio of the effusion rate of oxygen gas (o2) to that of sulfur dioxide gas (so2). express your answer in decimal form and calculate your answer to at least four sig figs.
The ratio of effusion rate of O₂ to SO₂ is 2.526
What is effusion rate?Effusion rate refers to the speed at which a gas passes through a small opening and enters a vacuum or an area of lower pressure.. It depends on the size of the hole, the pressure of the gas, and the molecular weight of the gas. Lighter gases effuse faster than heavier gases. The effusion rate is directly proportional to the velocity of the gas molecules, which is in turn proportional to the square root of the temperature of the gas.
Equation:Effusion rate of a gas is inversely proportional to the square root of its molar mass.
The molar mass of O₂ is 2 × 15.999 g/mol = 31.998 g/mol.
The molar mass of SO₂ is 32.066 g/mol + 2 × 15.999 g/mol = 64.064 g/mol.
The ratio of their effusion rates is:
√(64.064 g/mol) / √(31.998 g/mol) = 2.526
Rounded to four significant figures, the ratio is 2.526.
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draw the structure of a phosphatidyl choline that contains glycerol, oleic acid, stearic acid, and choline.
Phosphatidylcholine is a type of phospholipid that is commonly found in cell membranes. It is composed of a glycerol backbone, two fatty acid chains (one oleic acid and one stearic acid), a phosphate group, and a choline molecule.
To draw the structure of a phosphatidylcholine that contains glycerol, oleic acid, stearic acid, and choline, follow these steps:
1. Start by drawing the glycerol backbone, which consists of a central carbon atom with three hydroxyl (-OH) groups attached to it.
2. Attach the two fatty acid chains to the glycerol backbone. The oleic acid should be attached to the first carbon atom of the glycerol, while the stearic acid should be attached to the third carbon atom.
3. Draw a phosphate group attached to the second carbon atom of the glycerol backbone.
4. Finally, attach a choline molecule to the phosphate group. The choline molecule consists of a nitrogen atom attached to three methyl groups and a hydroxyl group.
Your final structure of Phosphatidylcholine should look like this:
Oleic acid - O - CH2 - CH - CH2 - C - O - CH2 - CH - (glycerol backbone) - CH - CH2 - COOH
|| ||
|| ||
OH OH
|
P
|
O-
|
CH2 - CH2 - N(CH3)3 - OH
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a 30 ml sample of 0.15m hydrazine (kb =1.3x10-6) is being titrated with 0.2m hclo4. what is the when 10 ml of acid are added after the equivalence point?
By considering the concentrations of these two species as well as the p K an of the weak acid, the Henderson-Hasselbalch equation enables you to determine the pH of a buffer solution that comprises a weak acid and its conjugate base.
Hypochlorous acid (HClO), in your situation, is the weak acid. One of its salts, potassium hypochlorite, or KClO, introduces the hypochlorite anion, the conjugate base of the compound, into the solution.Make an educated guess as to what the solution's pH will be in relation to the acid's p K a before performing any calculations. Be aware that the log term will equal zero if the weak acid and conjugate base concentrations are equal.
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In a galvanic cell, a spontaneous redox reaction occurs. However, the reactants are separated such that the transfer of electrons is forced to occur across a wire. The resulting electricity is measured in volts (V\rm V) and is the sum of the potentials of the oxidation and reduction half-reactions:
E?cell=E?red+E?ox{E^\circ}_{\rm cell} = {E^\circ}_{\rm red}+ {E^\circ}_{\rm ox}
Which is sometimes also written as:
E?cell=E?red(cathode)?E?red(anode){E^\circ}_{\rm cell} = {E^\circ}_{\rm red}{(\rm cathode)} - {E^\circ}_{\rm red}(\rm anode)
A table of standard reduction potentials gives E?red{E^\circ}_{\rm red}values for common half-reactions.
Reduction half-reaction E?E^\circ(V\rm V)
Ag+(aq)+e??Ag(s)\rm Ag^+{(aq)}+e^- \rightarrow Ag{(s)} 0.80
Cu2+(aq)+2e??Cu(s)\rm Cu^{2+}{(aq)}+2e^- \rightarrow Cu{(s)} 0.34
Ni2+(aq)+2e??Ni(s)\rm Ni^{2+}{(aq)}+2e^- \rightarrow Ni{(s)} ?-0.26
Fe2+(aq)+2e??Fe(s)\rm Fe^{2+}{(aq)}+2e^- \rightarrow Fe{(s)} ?-0.45
Zn2+(aq)+2e??Zn(s)\rm Zn^{2+}{(aq)}+2e^- \rightarrow Zn{(s)} ?-0.76
By reversing any of these reduction half-reactions, you get the corresponding oxidation half-reaction, for which E?ox{E^\circ}_{\rm ox}has the opposite sign of E?red{E^\circ}_{\rm red}.
Part A
Calculate the standard potential for the following galvanic cell:
Ni(s) | Ni2+(aq) | Ag+(aq) | Ag(s)\rm Ni (s)~ | ~ Ni^{2+}{(aq)}~ | ~Ag^{+}{(aq)}~ |~ Ag {(s)}
Express your answer to three significant figures and include the appropriate units.
Part B
In the context of the nickel-silver cell described in Part A, match each of the following descriptions to the anode or cathode.
Drag the appropriate items to their respective bins.
Cathode or Anode
a) Ni b) Ag c) gain mass d) losses mass e) positive electrode f) negative electrode g) attracts electrons h)stronger reducing agent.
Part A: E°cell = 0.80 V - (-0.26 V) = 1.06 V, The standard potential for the given galvanic cell is 1.06 V.
Part B: Anode: a) Ni, e) negative electrode, d) loses mass, h) stronger reducing agent and Cathode: b) Ag, f) positive electrode, c) gain mass, g) attracts electrons.
Part A:
To calculate the standard potential for the given galvanic cell, we use the formula first, we need to identify the cathode and anode in the cell. The cathode is where reduction occurs, and the anode is where oxidation occurs.
From the given half-reactions:
E°cell = E°red(cathode) - E°red(anode)
From the table of standard reduction potentials, we have:
E°red(Ni2+(aq) + 2e⁻ → Ni(s)) = -0.26 V
E°red(Ag+(aq) + e⁻ → Ag(s)) = 0.80 V
Since Ag has a higher reduction potential, it will act as the cathode and Ni will act as the anode. Now, we can plug the values into the formula:
E°cell = 0.80 V - (-0.26 V) = 1.06 V
Therefore, the standard potential for the given galvanic cell is 1.06 V.
Part B:
a) Ni - anode
b) Ag - cathode
c) gain mass - cathode
d) losses mass - anode
e) positive electrode - cathode
f) negative electrode - anode
g) attracts electrons - cathode
h) stronger reducing agent - cathode
So we can say that :
Anode: a) Ni, e) negative electrode, d) loses mass, h) stronger reducing agent
Cathode: b) Ag, f) positive electrode, c) gain mass, g) attracts electrons
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for the reaction 2a → 2b c, the rate constant value was determined to be 0.020 m/min. the initial concentration of a was 0.50 m. calculate the concentration of a after 7.0 minutes.
For reaction 2a → 2b + c, the given rate constant value is 0.020 m/min.
As the unit of the rate constant is molarity/min, therefore it will be a zero-order reaction.
Since this is a zero-order reaction, the rate of the reaction is constant and independent of the concentration of a.
Here, the rate of the reaction is equal to the rate constant (k) as shown below.
Rate of reaction = k = 0.020 M/min
We can use the rate law equation for zero-order reactions to calculate the concentration a after a certain time:
Rate = -Δ[A]/Δt
= k[A]^0
= k
here [A] is the concentration of a at any given time.
To solve for [A], one can rearrange the equation:
Δ[A] = -kΔt
[A]t = [A]0 - kΔt
Here;
[A]t is the concentration of a after time t
[A]0 is the initial concentration of a
Δt is the time elapsed
Putting the given values in the above equation:
[A]t = 0.50 M - (0.020 M/min)(7.0 min)
[A]t = 0.50 M - 0.14 M [A]t
[A]t = 0.36 M
Therefore, the concentration of a after 7.0 minutes is 0.36 M.
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