a) Calculate the standard reaction entropy for the combustion of methane to carbon dioxide and liquid water at 298 K. b) Calculate the standard reaction entropy for the hydrolysis of liquid water to form oxygen and hydrogen gas. c) Do your results in (a) and (b) agree with the general rule that reaction entropies are positive if there is a net formation of gas in a reaction, and negative if the is a net reduction of gas?

Answers

Answer 1

Answer: (a) [tex]\Delta S^{0}[/tex] = - 242.2J/K.mol

              (b) [tex]\Delta S^{0}[/tex] = 163.34J/K.mol

              (c) Yes

Explanation: Entropy is the measure of randomness or disorder of a system. Standard Entropy has the symbol [tex]S^{0}[/tex].

Mathematically, Entropy is defined as

[tex]\Delta S^{0}=\Sigma S^{0}(products)-\Sigma S^{0}(reagents)[/tex]

Each substance has its own entropy value.

(a) Combustion of Methane:

[tex]CH_{4}+2O_{2}[/tex] ⇒ [tex]CO_{2}+2H_{2}O[/tex]

Using standard entropy table, entropy will be:

[tex]\Sigma S^{0}(products)=214+2(69.91)[/tex] = 353.8

[tex]\Sigma S^{0}=186.264+2(205.138)[/tex] = 596.54

[tex]\Delta S^{0}=[/tex] 353.8 - 596.54

[tex]\Delta S^{0}=[/tex] - 242.2

Standard Entropy for combustion of methane is [tex]\Delta S^{0}=[/tex] - 242.2 J/K.mol.

(b) Hydrolysis of Water:

[tex]H_{2}O_{(l)}[/tex] ⇒ [tex]H_{2}_{(g)}+1/2O_{2}_{(g)}[/tex]

[tex]\Sigma S^{0}(products)=130.684+0.5(205.138)[/tex] = 233.253

[tex]\Sigma S^{0}(reagents)=69.91[/tex]

[tex]\Delta S^{0}=[/tex] 233.253 - 69.91

[tex]\Delta S^{0}=[/tex] +163.34

Standard Entropy for hydrolysis of water is [tex]\Delta S^{0}=[/tex] + 163.34 J/K.mol

(c) Yes, the results prove the general rule: Reactions Entropies are positive for net formation of gas and negative for net reduction of gas. This happens because, as entropy is the measure of disorder, the entropy for gases are greater than for liquids and solids. So, when there is formation of a gas, Entropy increases and when there isn't, entropy decreases.


Related Questions

Amino acids are the building blocks of proteins. The simplest amino acid is glycine (H2NCH2COOH). Draw a Lewis structure for glycine. (Hint: The central atoms in the skeletal structure are nitrogen bonded to carbon, which is bonded to another carbon. The two oxygen atoms are bonded directly to the right-most carbon atom.) Draw the molecule by placing atoms on the grid and connecting them with bonds. Include all hydrogen atoms and nonbonding electrons.

Answers

Answer:

Explanation:

The lewis structure (indicating all the atoms and patterns provided as hint in the question) of glycine can be seen in the attachment below. While the chemical structure of glycine can be seen below

         H

          |

H₂N - C - C =O

          |      \

         H      OH

The structure (of glycine) above provides a "fair idea" of how the lewis structure will be.

A chemical equation is balanced when the

subscripts of the reactants equal the subscripts of the products,
coefficients of the reactants equal the coefficients of the products,
products and reactants are the same chemicals,
same number of each kind of atom appears in the reactants and in the products,

Answers

same number of each kind of atom appears in the reactants and in the products

A piece of iron has a density of 7.87 grams per milliliters. It has a mass of 78.7 grams. What is the volume of the piece of iron?

Answers

The volume of a piece of iron with a density of 7.87 and mass of 78.7 would be 10cm^3

Consider the amino acid below, which is called alanine

Which atoms give the amino acid its unique chemical and physical properties?
A.the CH3 group
B. the amino groups
C. the oxygen atom
D. the hydrogen atom

Answers

A- the CH3 group

Just answered

Answer:

A) the CH3 group

Explanation:

How many moles are I 24.0x10^18 molecules NaOH?

Answers

Answer:

[tex] \huge 3.986 \times { 10}^{ - 5} \: \: mol \\ [/tex]

Explanation:

To find the number of moles in a substance given it's number of entities we use the formula

[tex]n = \frac{N}{L} \\[/tex]

where n is the number of moles

N is the number of entities

L is the Avogadro's constant which is

6.02 × 10²³ entities

From the question we have

[tex]n = \frac{24 \times {10}^{18} }{6.02 \times {10}^{23} } \\ \\ = 3.986 \times { 10}^{ - 5} \: \: mol[/tex]

Hope this helps you

Please Help!

Your car has 1.95 gallons of gasoline (octane, d = 0.6916 g/mL), which reacts with oxygen
according to the balanced reaction below. Your car uses the energy produced by this reaction
at a rate of 115 kJ per second while traveling at a speed of 65 miles per hour. Calculate the
distance (in miles) the car can travel using this amount of octane.
2 C8H18(g) + 25 O2(g) -----> 16 CO2(g) + 18 H2O(g) ΔHrxn = -10,900 kJ

Answers

Answer:

38.3 miles

Explanation:

First, we convert 1.95 gallons to mililiters:

1.95 gallons * [tex]\frac{3.785 L}{1gallon}*\frac{1000mL}{1 L}[/tex]= 7380.75 mL

Then we calculate how many grams of octane are available for the reaction, using its density:

0.6916 g/mL * 7380.75 mL = 5104.53 g C₈H₁₈

Now we convert octane grams into octane moles, using its molar mass:

5104.53 g C₈H₁₈ ÷ 114 g/mol = 44.78 mol C₈H₁₈

Then we calculate how many kJ are produced from the combustion of  44.78 mol C₈H₁₈, if 2 moles produce 10900 kJ:

44.78 mol * 10900 kJ / 2 mol = 244032 kJ

We calculate how many seconds is the car available to keep going, if it spends 115 kJ per second:

244032 kJ * 1 s / 115 kJ = 2122.02 s

We convert seconds to hours:

2122.02 / 3600 = 0.59 hours

Finally we calculate the distance:

65 mi/hour * 0.59 hour = 38.3 mi

Now, let's solve our problem using Boyle's Law:
A gas that exerts a pressure of 151 mm Hg in a
container with a volume of
L will exert a
pressure of 166 mm Hg when transferred to a
container with a volume of 0.532 L.
[?]L
Assume that the number of moles and the
temperature remain constant.

Answers

Answer:

V₁ = 0.585 L

Explanation:

Given data:

Initial pressure = 151 mmHg

Initial volume = ?

Final pressure = 166 mmHg

Final volume = 0.532 L

Solution:

The given problem will be solved through the Boyle's law,

"The volume of given amount of gas is inversely proportional to its pressure by keeping the temperature and number of moles constant"

Mathematical expression:

P₁V₁ = P₂V₂

P₁ = Initial pressure

V₁ = initial volume

P₂ = final pressure

V₂ = final volume  

Now we will put the values in formula,

P₁V₁ = P₂V₂

151 mmHg × V₁ = 166 mmHg × 0.532 L

V₁ = 166 mmHg × 0.532 L / 151 mmHg

V₁ = 88.312mmHg .L /151 mmHg

V₁ = 0.585 L

just write a C.E.R (claim, evidence, reasoning)​

Answers

Answer:

I have attached pictures below. Maybe those will help?

Explanation:

Answer:

this is  a CER model i did for science

Explanation:

claim : Tissue engineering is good for the future and has a positive impact on the future because tissue engineering restores aged, damaged or lost tissues/organs with artificial tissues in a way past medicines or technology has not.

evidence: The infographic states, “This science field provides opportunities for helping many people replace dead or injured organs with new ones. In doing so, it will give them a healthier, more productive life. This field is just beginning, and it is sure to change the length and quality of life of many people in the future.“

reasoning: Many people can benefit from tissue engineering because they can have dead or injured organs replaced with new ones. Tissue engineering is just the beginning and is still being conducted and tested , but as technology gets more advanced and advanced, tissue engineering will improve peoples lives the way medicines and past technology has never done.

what is the volume of a book that has a width of 10cm,a length that is 2 times the width,and a height that is half the width​

Answers

width=10cm

length=2xwidth=2x10=20cm

height=width/2=10/2=5

V=w*l*h=10*20*5=1000cm^3

Answer:

1000cm^3

Explanation:

first collect what is known

width 10cm

length 2×width (2×10cm) =20cm

height width/2 (10cm/2) =5cm

now if we use the formula for finding volume of a cuboid that has length, width and height known;

V = l×w×h

= 20cm × 10cm × 5cm

= 1000cm^3

A biochemist carefully measures the molarity of magnesium ion in of cell growth medium to be . Unfortunately, a careless graduate student forgets to cover the container of growth medium and a substantial amount of the solvent evaporates. The volume of the cell growth medium falls to . Calculate the new molarity of magnesium ion in the cell growth medium. Be sure your answer has the correct number of significant digits.

Answers

Answer:

760 uM

Explanation:

A biochemist carefully measures the molarity of magnesium ion in 47, mL of cell growth medium to be 97 uM. Unfortunately, a careless graduate student forgets to cover the container of growth medium and a substantial amount of the solvent evaporates. The volume of the cell growth medium falls to 6.0 mL. Calculate the new molarity of magnesium ion in the cell growth medium Be sure your answer has the correct number of significant digits.

The problem here is that the amount of magnesium ion remains the same irrespective of the volume.

Amount of magnesium in the growth medium = molarity x volume

    = 97 x [tex]10^{-6}[/tex] x 47 x [tex]10^{-3}[/tex] = 4.559 x [tex]10^{-6}[/tex]

Then, the volume reduced to 6.0 mL, the new molarity becomes;

molarity = mole/volume

       = 4.559 x [tex]10^{-6}[/tex]/6 x [tex]10^{-3}[/tex] = 7.598333 x [tex]10^{-4}[/tex] M = 759.83333 uM

To the correct number of significant digits = 760 uM

HELPPP PLEASEEE

is this
1: radiation
2: conduction
3: convection

Answers

Number 2: Conduction.

This is an example of #2, conduction.

Conduction is the process where heat energy is transmitted through collisions between atoms or molecules.

A sample is in the second half-life. What percent of the sample is stable at this point?


A. 12.5%

B. 25%

C. 50%

D. 75%

Answers

Answer:

75%

Explanation:

on edg :)

Please help will give brainliest

Answers

Answer:

Number of moles = 1.57 mol

Explanation:

Given data:

Mass of propanol = 94.1 g

Molar mass of propanol = 60.1 g/mol

Number of moles of propanol = ?

Solution:

Formula:

Number of moles = mass/molar mass

by putting values,

Number of moles = 94.1 g/ 60.1 g/mol

Number of moles = 1.57 mol

URGENT!!!
5. As the water temperature is increased
from 20°C to 90°C, how many more grams
of copper sulfate will dissolve in 100 grams
of water?
____g

Answers

Answer:

40

Explanation:

Because of gravity, your weight
on the Moon
A. would be the same as it is on Earth
B. would be less than your weight on Earth
C. would be more than your weight on Earth
D. and your mass would be less than it is on Earth

Answers

Answer:

the answer is b

Explanation:

brcause the gravutational pull on the moon is lower than on earth...

B, that’s why you feel like your floating on the moon

someone on this planet please help me with this vocab

Answers

Answer:

1 - concentrated solution

2- dilute solution

3- solubility

4- saturated solution

5- supersaturated solution

6- unsaturated solution

7- acid

8- base

9- corrosive

10- indicator

Explanation:

A limited number of the many known elements comprise the largest portion of living matter. Group Elements A Calcium, Phosphorus, Oxygen, Sulfur B Cobalt, Hydrogen, Oxygen, Nitrogen C с Helium, Oxygen, Sulfur, Carbon Hydrogen, Oxygen, Nitrogen, Carbon 1 1 Which group of elements above comprises the largest portion of living matter? A Group A B Group B C Group C D Group D​

Answers

Answer:

Explanation:

Hydrogen oxygen nitrogen and carbon

A football player kicks a 0.94 kg football with a force of 2.4 N.

Calculate the acceleration of the football as the player kicks the ball. Round your answer to the nearest tenth of a m/s2.

The acceleration of the football is

Answers

Explanation:

Fnet = ma

Therefore a = Fnet/m = 2.4N/0.94kg = 2.45m/s².

Answer:

2.6  m/s2

Explanation:

How is the kinetic energy of the particles of a substance affected during a phase change?
A.) Kinetic energy increases during exothermic changes and decreases during endothermic changes.
B.) Kinetic energy decreases during exothermic changes and increases during endothermic changes.
C.) Kinetic energy does not change, but the potential energy does.
D.) Kinetic energy changes in the opposite way that the potential energy changes.

Answers

Answer: A. Kinetic energy increases during exothermic changes and decreases during endothermic changes

Explanation: During an exothermic change potential energy is converted to kinetic energy. I hope this is correct. :)

Answer:

C

Explanation:

can someone help me with my chemistry on my page/account?

Answers

Answer:

Yes

Explanation:

Text me on here

Which force acts on falling objects to oppose gravity?
pull
terminal velocity
air resistance
acceleration

Answers

The answer is pull your welcome

Answer:pull

Explanation:

punnet squares, help how do I do this

Answers

Explanation:

Im not sure what the other trait is so I couldn't do phenotype. I hope this still helps though

Bruh I hate science Pls help me


List 5 physical properties of matter.



What is a chemical property?



List 2 chemical properties.



What is the difference between chemical property and chemical change?



List 3 products that are the results of chemical reactions.

Answers

Answer:

1. The properties of matter include any traits that can be measured, such as an object's density, color, mass, volume, length, malleability, melting point, hardness, odor, temperature, and more.

2. A chemical property is a characteristic of a particular substance that can be observed in a chemical reaction.

3. Toxicity and acidity.

4. A chemical property describes the ability of a substance to undergo a specific chemical change. A chemical reaction is a process that occurs when one or more substances are changed into one or more new substances.

5. The five basic types of chemical reactions are combination, decomposition, single-replacement, double-replacement, and combustion. Analyzing the reactants and products of a given reaction will allow you to place it into one of these categories. Some reactions will fit into more than one category.

Hope this helps you~

What else is produced when sodium carbonate decomposes?
Na2Co3 - Na2O+

Answers

Answer:When a single compound breaks down into two or more compounds or elements in a chemical reaction then it is known as decomposition reaction.

The chemical symbol for sodium carbonate is .

The decomposition of sodium carbonate is:

The decomposition of sodium bicarbonate,  will result in the formation of sodium oxide,  and carbon dioxide, .

Hence, carbon dioxide,  will produce with sodium oxide,  on decomposition of .

Explanation:Na2CO3 Na2O +CO2   CO2 is the answer

Mass of an empty 50 litres cylinder is 4.8kg. the cylinder is filled with 60atm nitrogen gas. molecular mass of nitrogen is 28. what is the new mass of cylinder​

Answers

Answer:

8.235 kg

Explanation:

Mass of the cylinder = 4.8 kg

The capacity (volume) of the cylinder = 50 liters

As 1 m^3 = 1000 liters

So, the volume of the cylinder, v= 0.05 m^3

The volume of filled nitrogen, v= 0.05 m^3

Pressure of filled nitrogen, p = 60 atm = 60\times 101325 Pa

Assuming that the nitrogen gas is at room temperature which is 25-degree centigrade,

So, the temperature of nitrogen gas, T=273+25= 298 K

By using the ideal gas equation, pv=nRT

Where n is the number of moles, R is the universal gas constant, R = 8.314 J/mol·K

Putting all the values in the ideal gas equation, we have

(60 x 101325)0.05 = n (8.314) x (298)

n= (60 x 101325 x 0.05)/(8.314 x 298)

n=122.69 moles

As the  molar mass of nitrogen is 28, so the total mass of the nitrogen in the cylinder, m= 122.69 x 28 = 3435.32 grams = 3.435 kg.

Hence, the new mass of the cylinder = 4.8+3.435=8.235 kg

The table shows four reactions.
Reactions
Reaction Equation
C₃ H8+ 50₂ 3C02 + 4H20
2Ca + O2- 2CaO
AgNO3 + NaCl
AGCI + NaNO3
CH3COOH + 202 - 2CO2 + 2H20
4
Which of the above reactions is an example of combustion of an Inorganic substance? (5 points)

Answers

Answer: 2

Explanation:

A combustion reaction must include O2 as a reactant.

An inorganic substance almost never includes carbon.

So, by process of elimination:

1. Carbon is a reactant = probably not

2. Has O2, no carbon = yes

3. O2 is not a reactant = no

4. Carbon is a reactant = probably not

An example of the combustion of an inorganic substance is:

2 Ca + O₂ ⇒ 2 CaO

We have 4 reactions and we want to determine which is an example of combustion of an inorganic substance.

What is combustion?

A combustion reaction is a reaction in which a substance reacts with oxygen gas, releasing energy in the form of light and heat.

What is the difference between organic and inorganic substances?

Organic substances always contain carbon while most inorganic substances do not contain carbon.

Let's consider the following reactions.

C₃H₈ + 5 O₂ ⇒ 3 CO₂ + 4 H₂O

This is a combustion reaction but C₃H₈ is an organic substance.

2 Ca + O₂ ⇒ 2 CaO

This is an example of the combustion of an inorganic substance.

AgNO₃ + NaCl ⇒ AgCI + NaNO₃

This is not a combustion reaction.

CH₃COOH + 2 O₂ ⇒ 2 CO₂ + 2 H₂O

This is a combustion reaction but CH₃COOH is an organic substance.

An example of the combustion of an inorganic substance is:

2 Ca + O₂ ⇒ 2 CaO

Learn more about combustion here: https://brainly.com/question/4155165

What is 797 mm hg to atm?

Answers

Answer:

797 mm hg = 1.04868 atm

Explanation:

1 atm = 760 mm hg

797 mm hg to atm is 1.0468 atm

Pressure is defined as the physical force exerted on an object. The force applied is perpendicular to the surface of objects per unit area.

There are many different types of units and prefixes that may be used in general practice to reflect pressure. Thus, it is ensured that all the measurements and their respective units are in the same framework when conducting pressure calculations.

Pascal is the SI unit of pressure, and is the basic pressure unit in the SI (the International System of Units) system.

Given,

Pressure = 797 atm

1 mm Hg = 0.00131579 atm

797 mm Hg = 0.00131579 × 797

= 1.04868 atm

Learn more about Pressure, here:

https://brainly.com/question/30673967

#SPJ1

How many hydrogen ions (H+) are in a mole?

Answers

6.02 × 10^23 hydrogen ions per mol

Which event would most likely lead to a thunderstorm g i v i n g b r a i n l e s i t HELP

Answers

Answer:

A

Explanation:

A is the correct answer once the warm, moist air moves into the cold, dry air, the thunderstorm will start to develop and gradually get larger.

In science why is it important to explain why the evidence supports your claim?

Answers

In science it’s important to explain the evidence that supports your claim because in science it’s more about what you willing to do
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